Abstract
The synthesis of W(OAr)2Cl(CHR)(CH2R 1)(OR22) (Ar = 2,6-disubstituted phenyl; R 2 = Et or Pri) illustrates one of the first examples of a well defined, Lewis acid-free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.
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CITATION STYLE
Quignard, F., Leconte, M., & Basset, J. M. (1985). Synthesis and catalytic properties of W(OAr)2Cl 2(CHCMe3)(OR2) and W(OAr) 2Cl(CHCMe3)(CH2CMe3)(OR 2) (Ar = 2,6-disubstituted phenyl; R = Et or Pri), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups. Journal of the Chemical Society, Chemical Communications, (24), 1816–1817. https://doi.org/10.1039/c39850001816
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