Interannual variability of terpenoid emissions in an alpine city

Abstract

Terpenoid emissions above urban areas are a complex mix of biogenic and anthropogenic emission sources. In line with previous studies we found that summertime terpenoid fluxes in an alpine city were dominated by biogenic sources. Inter-seasonal emission measurements revealed consistency for monoterpenes and sesquiterpenes but a large difference in isoprene between the summers of 2015 and 2018. Standardized emission potentials for monoterpenes and sesquiterpenes were 0.12g nmolg m-2g s-1 and 3.0×10-3g nmolg m-2g s-1 in 2015 and 0.11g nmolg m-2g s-1 and 3.4×10-3g nmolg m-2g s-1 in 2018, respectively. Observed isoprene fluxes were almost 3 times higher in 2018 than in 2015. This factor decreased to 2.3 after standardizing isoprene fluxes to 30g g C air temperature and photosynthetic active radiation (PAR) to 1000g μmolg m-2g s-1. Based on emission model parameterizations, increased leaf temperatures can explain some of these differences, but standardized isoprene emission potentials remained higher in 2018 when a heat wave persisted. These data suggest a higher variability of interannual isoprene fluxes than for other terpenes. Potential reasons for the observed differences such as emission parameterization, footprint changes, water stress conditions, and tree trimming are investigated.