A fast and simple method for the acylation of alcohols with acid chlorides promoted by metallic samarium

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Abstract

Acylation of primary, secondary, allyl and benzyl alcohols with acid chlorides promoted by samarium metal under neutral condition gave carboxylic acid esters in good to excellent yields. Acylation of a tertiary alcohol did not occur under the same reaction conditions.

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Jia, X. S., Wang, H. L., Huang, Q., Kong, L. L., & Zhang, W. H. (2006). A fast and simple method for the acylation of alcohols with acid chlorides promoted by metallic samarium. Journal of Chemical Research, (2), 135–138. https://doi.org/10.3184/030823406776330981

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