(E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one

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Abstract

In the title compound, C11H15NOS, the 3-(dimethylamino)-prop-2-en-1-one unit is approximately planar [maximum deviation = 0.0975 (14) Å] and its mean plane of seven non-H atoms makes a dihedral angle of 6.96 (10)°with the thiophene ring. In the crystal, molecules are linked by pairs of C - H⋯O hydrogen bonds into inversion dimers with R22(14) ring motifs. The dimers are stacked along the c axis through C - H⋯π interactions. The two methyl groups, attached to the thiophene ring and the amino N atom, are each disordered over two orientations, with site-occupancy ratios of 0.59 (4):0.41 (4) and 0.74 (4):0.26 (4), respectively.

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Ghorab, M. M., Al-Said, M. S., Ghabbour, H. A., Chia, T. S., & Fun, H. K. (2012). (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 68(6). https://doi.org/10.1107/S1600536812021022

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