Supraparticles for Bare-Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility

Abstract

Indicators for H2 are crucial to ensure safety standards in a green hydrogen economy. Herein, the authors report micron-scaled indicator supraparticles for real-time monitoring and irreversible recording of H2 gas via a rapid eye-readable two-step color change. They are produced via spray-drying SiO2 nanoparticles, Au-Pd nanoparticles, and indicator-dye resazurin. The resulting gas-accessible mesoporous supraparticle framework absorbs water from humid atmospheres to create a three-phase-system. In the presence of H2, the color of the supraparticle switches first irreversibly from purple to pink and further reversibly to a colorless state. In situ infrared spectroscopy measurements indicate that this color change originates from the (ir)reversible H2-induced reduction of resazurin to resorufin and hydroresorufin. Further infrared spectroscopic measurements and molecular dynamics simulations elucidate that key to achieve this functionality is an established three-phase-system within the supraparticles, granting molecular mobility of resazurin. Water acts as transport medium to carry resazurin molecules towards the catalytically active Au-Pd nanoparticles. The advantages of the supraparticles are their small dimensions, affordable and scalable production, fast response times, straightforward bare-eye detection, and the possibility of simultaneously monitoring H2 exposure in real-time and ex post. Therefore, H2 indicator supraparticles are an attractive safety additive for leakage detection and localization in a H2 economy.