A Neutral Beryllium(I) Radical

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Abstract

The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X-ray crystallography, and DFT calculations.

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Czernetzki, C., Arrowsmith, M., Fantuzzi, F., Gärtner, A., Tröster, T., Krummenacher, I., … Braunschweig, H. (2021). A Neutral Beryllium(I) Radical. Angewandte Chemie - International Edition, 60(38), 20776–20780. https://doi.org/10.1002/anie.202108405

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