Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans

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Abstract

Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoid pterocarpans. © 2007 Álvarez-Corral et al; licensee Beilstein Institut.

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Álvarez-Corral, M., López-Sánchez, C., Jiménez-González, L., Rosales, A., Muñoz-Dorado, M., & Rodríguez-García, I. (2007). Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans. Beilstein Journal of Organic Chemistry, 3. https://doi.org/10.1186/1860-5397-3-5

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