Synthesis of electron-poor hexa-peri-hexabenzocoronenes

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Abstract

The oxidative cyclodehydrogenation of electron-poor arenes was achieved using DDQ-CF3SO3H resulting in hexa-peri-hexabenzocoronenes with electron withdrawing Br, F and CF3 groups. This method will lead to their expansion into a new class of electron transport materials. © 2012 Royal Society of Chemistry.

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Jones, D. J., Purushothaman, B., Ji, S., Holmes, A. B., & Wong, W. W. H. (2012). Synthesis of electron-poor hexa-peri-hexabenzocoronenes. Chemical Communications, 48(65), 8066–8068. https://doi.org/10.1039/c2cc33892k

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