Metal and boron derivatives of fluorinated cyclic 1,3-dicarbonyl compounds

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Abstract

Starting from the corresponding cyclic 1,3-diketones or other precursors (cyclic ketones as well as lactones), several new salts and chelate complexes of fluorinated 1,3-dicarbonyls were obtained. Their preparative significance was demonstrated by straightforward syntheses of fluorinated pyrazoles, benzimidazoles and 1,7-ketoesters. The structure of a boron chelate of 2-(trifluoroacetyl)- cyclohexanone was investigated by X-ray diffraction. © 2009 Verlag der Zeitschrift für Naturforschung, Tübingen.

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Sevenard, D. V., Khomutov, O. G., Boltachova, N. S., Filyakova, V. I., Vogel, V., Lork, E., … Röschenthalerc, G. V. (2009). Metal and boron derivatives of fluorinated cyclic 1,3-dicarbonyl compounds. Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences, 64(5), 541–550. https://doi.org/10.1515/znb-2009-0510

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