High energy density MnO4-/MnO42- redox couple for alkaline redox flow batteries

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Abstract

The MnO4-/MnO42- redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature. Careful optimization of the electrolyte composition and the potential limits eliminates the side reactions, making this redox couple an attractive option for alkaline redox flow batteries.

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Colli, A. N., Peljo, P., & Girault, H. H. (2016). High energy density MnO4-/MnO42- redox couple for alkaline redox flow batteries. Chemical Communications, 52(97), 14039–14042. https://doi.org/10.1039/c6cc08070g

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