Removal of Methylene Blue from aqueous solution by marine green alga Ulva lactuca

Abstract

Biosorption of colours is an important technology for treatment of different types of industrial wastewaters containing dyes. The objective of this study was to convert green alga Ulva lactuca to dye adsorbents for wastewater treatment. The importance of commonly available green alga Ulva lactuca was investigated as viable biomaterials for the biological treatment of synthetic basic blue 9 (5-ch1oro- N, N, N', N'- tetramethyl-5λ4-phenothiazine-3,7-diamine) effluents. The results obtained from the batch experiments revealed the ability of the green algae to remove the basic blue 9, and this was dependent on the dye concentration, pH, and algal biomass. We investigated the equilibrium and kinetics of adsorption, and the Langmuir and Freundlich equations were used to fit the equilibrium isotherm. The adsorption isotherm of basic blue 9 followed both the Langmuir and Freundlich models with a correlation coefficient of ∼0.96-0.99, and the adsorption kinetics followed the pseudo-second-order model ( R2 =1.0). The maximum adsorption capacity was about 40.2mg of dye per gram of dry green algae at pH 10, 25g l-1 dye and 2.5g l-1 alga concentrations. This study demonstrated that the green algae could be used as an effective biosorbent for the treatment of dye-containing wastewater streams. © 2006 Taylor & Francis.