Abstract
Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (CrI and CrII), which are important species in the formation of type I quintuple-bonded complexes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Huang, Y. L., Lu, D. Y., Yu, H. C., Yu, J. S. K., Hsu, C. W., Kuo, T. S., … Tsai, Y. C. (2012). Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination. Angewandte Chemie - International Edition, 51(31), 7781–7785. https://doi.org/10.1002/anie.201202337
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