Abstract
The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson-Claisen rearrangement, asymmetric Mukaiyama aldol reaction and MNBA-mediated lactonization.
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Tonoi, T., Mameda, K., Fujishiro, M., Yoshinaga, Y., & Shiina, I. (2014). Total synthesis of the proposed structure of astakolactin. Beilstein Journal of Organic Chemistry, 10, 2421–2427. https://doi.org/10.3762/bjoc.10.252
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