Chemically crosslinked isoreticular metal-organic frameworks

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Abstract

Herein we report the synthesis of canonical isoreticular metal-organic frameworks (IRMOFs) containing interligand crosslinks. Chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties. © 2013 Royal Society of Chemistry.

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Allen, C. A., Boissonnault, J. A., Cirera, J., Gulland, R., Paesani, F., & Cohen, S. M. (2013). Chemically crosslinked isoreticular metal-organic frameworks. Chemical Communications, 49(31), 3200–3202. https://doi.org/10.1039/c3cc40635k

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