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Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones

Synthesis (Germany) (2019) 51(1) 203-212
DOI: 10.1055/s-0037-1610391
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Abstract

A sequential benzoylation and multihetero-Cope rearrangement of α-keto ester derived nitrones has been developed. The reaction furnishes a diverse array of complex α-imino ester derivatives. The products can be transformed into amino alcohols via LiAlH 4 reduction.

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Bartlett, S. L., Keiter, K. M., Zavesky, B. P., & Johnson, J. S. (2019). Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones. Synthesis (Germany), 51(1), 203–212. https://doi.org/10.1055/s-0037-1610391

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