Characterization and mechanical properties of foamed poly(ε-caprolactone) and Mater-Bi blends using CO2 as blowing agent

Abstract

Biodegradable foams are a key area of growth for packaging applications. Starch-based materials have been a successful environmentally degradable polymer. However, making foams out of these materials has been challenging due to their chemical composition and consequent low miscibility in CO2. We examine the potential for developing biodegradable foams with one component being a starch-based polymer by introducing it into polycaprolactone. Polycaprolactone has thus far shown very high-expansion ratios for foams with supercritical CO2. Blends with increasing amounts of starch-based materials were processed and foamed using isothermal treatments with supercritical CO2. Characterization of the samples was done using X-ray diffraction, differential scanning calorimetry, and scanning electron microscopy. The melting enthalpies and temperatures of the starch-based materials phase decreased with decreasing starch-based materials indicating some an influence of polycaprolactone on the starch-based materials crystallinity. Foaming, however, caused a reversal in this effect with the foamed melting points similar to the pure components. Micrographs of the samples from the scanning electron microscopy revealed that the cell size of the foams reduced with the increase in starch-based materials concentration. Mechanical tests - tensile, compression, shear, and impact - were performed on the foamed samples. The results indicate a valuable approach to foaming materials that are compostable but not CO2 miscible through blending with a highly foamable polymer such as polycaprolactone.