Thermal and near-infrared light induced spin crossover in a mononuclear iron(II) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

F. Pointillart; X. Liu; M. Kepenekian; B. Le Guennic; S. Golhen; V. Dorcet; T. Roisnel; O. Cador; Z. You; J. Hauser; S. Decurtins; L. Ouahab; S. X. Liu

Journal ArticleOPEN ACCESS

Thermal and near-infrared light induced spin crossover in a mononuclear iron(II) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

Dalton Transactions (2016) 45(28) 11267-11271

DOI: 10.1039/c6dt00920d

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Abstract

A mononuclear Fe(ii) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.

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Pointillart, F., Liu, X., Kepenekian, M., Le Guennic, B., Golhen, S., Dorcet, V., … Liu, S. X. (2016). Thermal and near-infrared light induced spin crossover in a mononuclear iron(II) complex with a tetrathiafulvalene-fused dipyridophenazine ligand. Dalton Transactions, 45(28), 11267–11271. https://doi.org/10.1039/c6dt00920d

Thermal and near-infrared light induced spin crossover in a mononuclear iron(II) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

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