Dibromoindium(iii) cations as a π-Lewis acid: Characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

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Abstract

[IPr·InBr2][SbF6] (2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has been synthesized and characterized in the solid state. This complex proved to be a very active catalyst for hydroarylations, transfer hydrogenations, and cycloisomerizations.

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Michelet, B., Colard-Itté, J. R., Thiery, G., Guillot, R., Bour, C., & Gandon, V. (2015). Dibromoindium(iii) cations as a π-Lewis acid: Characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes. Chemical Communications, 51(34), 7401–7404. https://doi.org/10.1039/c5cc00740b

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