High temperature gas sensing performances of silicon carbide nanosheets with an n-p conductivity transition

Abstract

Fast and effective detecting of flammable and explosive gases in harsh environments (high temperature, corrosion atmosphere) is crucial for preventing severe accidents for the chemical industry, fuel cell applications and engine tests. Silicon carbide material is reported to be a good candidate for gas sensing devices applied in extreme conditions. Herein, high-temperature available silicon carbide nanosheets (SiC NSs) were synthesized from graphene oxide (GO) via a catalyst-free carbothermal method. The structure and composition of SiC NSs under different reaction conditions are carefully characterized. The received SiC NSs were firstly utilized as gas sensing materials for hazardous gases (acetone, ethanol, methanol and ammonia) at a high temperature (500 °C). Importantly, the SiC NSs sensors exhibited a fast response (8-39 s) and recovery (12-69 s) towards detecting gases. Besides, an n-p conductivity transition phenomenon is found and studied. This paper firstly proves that such SiC NSs has the potential to be used in gas sensing fields.