Variable dimensionality in 'hollow' hybrid tin iodide perovskites

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Abstract

Two 'hollow' B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.

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McNulty, J. A., Slawin, A. M. Z., & Lightfoot, P. (2020). Variable dimensionality in “hollow” hybrid tin iodide perovskites. Dalton Transactions, 49(43), 15171–15174. https://doi.org/10.1039/d0dt03449e

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