4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagomé lattice and the M6L 12 octahedron

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Abstract

Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3·2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron. Copyright © 2005 American Chemical Society.

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Liu, Y., Kravtsov, V. C., Beauchamp, D. A., Eubank, J. F., & Eddaoudi, M. (2005). 4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagomé lattice and the M6L 12 octahedron. Journal of the American Chemical Society, 127(20), 7266–7267. https://doi.org/10.1021/ja051259q

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