Intrinsic resonance representation of quantum mechanics

7Citations
Citations of this article
6Readers
Mendeley users who have this article in their library.
Get full text

Abstract

The choice of basis states in quantum calculations can be influenced by several requirements, and sometimes a very natural basis suggests itself. However often one retreats to a "merely complete" basis, whose coefficients in the eigenstates carry little physical insight. We suggest here an optimal representation, based purely on classical mechanics. "Hidden" constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leaving the quantum effects to be isolated and included by small matrix diagonalizations. This simplifies the hierarchical structure of couplings between "zero-order" states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamilton-Jacobi equation. © 1997 American Institute of Physics.

Cite

CITATION STYLE

APA

Carioli, M., Heller, E. J., & Møller, K. B. (1997). Intrinsic resonance representation of quantum mechanics. Journal of Chemical Physics, 106(20), 8564–8571. https://doi.org/10.1063/1.473911

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free