Abstract
Heteroleptic zinc(i) complexes L1,2Zn-ZnCp* (L1= HC[C(CF3)NC6F5]21; L2= HC[C(Me)NDipp]2; Dipp = 2,6-i-Pr2C6H32) are synthesized by reactions of Cp*2Zn2with L1H and L2ZnH. 2 reacts witht-BuNCO to give unprecedented carbamate complex (4), while reactions with RN3gave bis-hexazene, triazenide, and trimeric azide complexes (5-7).
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CITATION STYLE
APA
Li, B., Huse, K., Wölper, C., & Schulz, S. (2021). Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes. Chemical Communications, 57(100), 13692–13695. https://doi.org/10.1039/d1cc05617d
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