Catalytic liquid phase oxidation of 1,4-dioxane over a Pt/CeO2-ZrO2-Bi2O3/SBA-16 catalyst

Abstract

A Pt/CeO2-ZrO2-Bi2O3/SBA-16 (Santa Barbara Amorphous No. 16) catalyst was prepared by hydrothermal and wet impregnation methods for catalytic purification of 1,4-dioxane in water. SBA-16 has a number of mesopores and the average size of the pores is 9.4 nm. In the present catalyst, platinum and CeO2-ZrO2-Bi2O3 were successfully dispersed in the pores of the SBA-16 support, and the temperature dependence of the liquid phase oxidation of 1,4-dioxane was examined. The oxidation reaction proceeded effectively in the air atmosphere in the temperature range of 40–80 °C.