Condensed-matter equation of states covering a wide region of pressure studied experimentally

Abstract

The relationships among the pressure P, volume V, and temperature T of solid-state materials are described by their equations of state (EOSs), which are often derived from the consideration of the finite-strain energy or the interatomic potential. These EOSs consist of typically three parameters to determine from experimental P-V-T data by fitting analyses. In the empirical approach to EOSs, one either refines such fitting parameters or improves the mathematical functions to better simulate the experimental data. Despite over seven decades of studies on EOSs, none has been found to be accurate for all types of solids over the whole temperature and pressure ranges studied experimentally. Here we show that the simple empirical EOS, P = α1 (PV) + α2 (PV)2 + α3 (PV)3, in which the pressure P is indirectly related to the volume V through a cubic polynomial of the energy term PV with three fitting parameters α1-α3, provides accurate descriptions for the P-vs-V data of condensed matter in a wide region of pressure studied experimentally even in the presence of phase transitions.