Nanostructured layered double hydroxide (NLDH) - Zn/Al-based materials: strategy to improve performance for zirconium sorption from acidic sulfate solution

Abstract

Zirconium is a highly stable radionuclide commonly used in various nuclear operations. However, removing zirconium from wastewater streams is crucial to protect the environment and human health. To achieve this, a zinc and aluminum nanostructured layered double hydroxide (Zn/Al-NLDH) was prepared and investigated for effective removal of zirconium from aqueous solutions. This study examined the prepared Zn/Al-NLDH's structural and textural properties and the impact of various factors on its adsorption performance. The Langmuir isotherm and Pseudo-second order kinetic models were found to be the best fit for the adsorption process of Zr(vi). This suggests that the adsorption process is uniform, involves the formation of a monolayer, and is chemisorption in nature. The maximum uptake capacity was 117.6 mg g−1, and the process was endothermic, spontaneous, and feasible. About 96% of Zr(vi) was successfully desorbed from the loaded sorbent using 1.0 M hydrochloric acid, and the Zn/Al-NLDH sorbent remained stable for six consecutive sorption/desorption cycles. These findings emphasize the high potential of Zn/Al-NLDH to act as a remarkable sorbent for efficiently tackling water contaminants.