Abstract
Ageing and dealkylation of Soman-inactivated electric eel cholinesterase occur at essentially identical rates and are catalyzed by an acidic group in the enzyme with a pKa′ of 6.4. Dealkylation of Soman-inactivated electric eel cholinesterase takes place by a carbonium ion mechanism with the production of 2,3-dimethyl-2-butanol; 2,3-dimethyl-1-butene; and 2,3-dimethyl-2-butene. © 1967.
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CITATION STYLE
Michel, H. O., Hackley, B. E., Berkowitz, L., List, G., Hackley, E. B., Gillilan, W., & Pankau, M. (1967). Ageing and dealkylation of soman (pinacolylmethylphosphonofluoridate)-inactivated eel cholinesterase. Archives of Biochemistry and Biophysics, 121(1), 29–34. https://doi.org/10.1016/0003-9861(67)90006-9
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