Modeling the removal of Reactive Red 120 dye from aqueous effluents by activated carbon

Abstract

The adsorption isotherms of Reactive Red 120 (RR-120) on Brazilian pine-fruit shell activated carbon, at six temperatures (298, 303, 308, 313, 318 and 323 K) and pH ¼ 6, were determined and interpreted using a double layer model with one energy. A statistical physics treatment established the formulation of this model. Steric and energetic parameters related to the adsorption process, such as the number of adsorbed molecules per site, the receptor sites density and the concentration at half-saturation, have been considered. Thermodynamic potential functions such as entropy, internal energy and Gibbs free enthalpy are analyzed, and the choice of the models is based on assumptions in correlation with experimental conditions. By numerical fitting, the investigated parameters were deduced. The theoretical expressions provide a good understanding and interpretation of the adsorption isotherms at the microscopic level. We believe that our work contributes to new theoretical insights on the dye adsorption in order to know the physical nature of the adsorption process.