Molecular Wires for Efficient Long-Distance Triplet Energy Transfer

Abstract

We propose design rules for building organic molecular bridges that enable coherent long-distance triplet-exciton transfer. Using these rules, we describe example polychromophoric structures with low inner-sphere exciton reorganization energies, low static and dynamic disorder, and enhanced π-stacking interactions between nearest-neighbor chromophores. These features lead to triplet-exciton eigenstates that are delocalized over several units at room temperature. The use of such bridges in donor-bridge-acceptor assemblies enables fast triplet-exciton transport over very long distances that is rate-limited by the donor-bridge injection and bridge-acceptor trapping rates.