Journal Article

Chemistry of the Sulfur-Nitrogen Bond. II.1 a Mechanistic Study of the Rearrangement of 2-Nitrobenzenesulfenanilides to 2-Aminobenzenesulfonanilides

Journal of Organic Chemistry (1972) 37(6) 854-859
DOI: 10.1021/jo00971a009
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Abstract

2-Nitrobenzenesulfenanilides thermally rearranged to give, among other products, 2-aminobenzenesulfonani-lides. A mechanistic scheme is proposed which involves homolytic cleavage of the sulfur-nitrogen bond and transfer of a hydrogen atom from the solvent. © 1972, American Chemical Society. All rights reserved.

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Davis, F. A., & Johnston, R. P. (1972). Chemistry of the Sulfur-Nitrogen Bond. II.1 a Mechanistic Study of the Rearrangement of 2-Nitrobenzenesulfenanilides to 2-Aminobenzenesulfonanilides. Journal of Organic Chemistry, 37(6), 854–859. https://doi.org/10.1021/jo00971a009

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