Reutealis trisperma oil esterification: Optimization and kinetic study

Abstract

Reutealis trisperma, due to its high kernel-oil yield (±50%) and long productivity (±70 years), is considered to be a promising feedstock for biodiesel production. In addition, this plant, which can thrive on marginal lands, is classified as a non-edible oil since it contains a toxin known as eleostearic acid. The present study aimed to optimize the esterification step in biodiesel production from R.trisperma oil catalyzed using sulfonic ion exchange resin Lewatit K2640. The optimization step was performed using a response surface methodology through the incorporation of a central composite design. A kinetic study was performed as well, based on the assumption of a pseudo-homogeneous second-order model. Catalyst loading was found to have the most significant impact on acid value, followed by temperature and methanol-to-oil molar ratio. The optimal conditions for the esterification step were 92 ◦C temperature, 5.34% catalyst loading, and 5.82:1 methanol-to-oil molar ratio. The acid value and FFA conversion of R.trisperma oil under these conditions were 2.49 mg KOH/g and 91.75%, respectively. The kinetics study revealed that the constructed model could fit the experimental data well with relatively high reliability. The activation energy required for the esterification of R.trisperma oil was 33.2 kJ/mol.