Abstract
Five new cyclopropyl-ketoacids were prepared in good yields from monoterpenic olefines using solid-liquid phase transfer catalysis (SL-PTC) dichlorocyclopropanation reaction followed by oxidative cleavage with RuCl 3-NaIO4 system. The nonchlorinated cyclopropanes were obtained by sodium/methanol reduction of the corresponding gem- dichlorocyclopropanes. ©ARKAT.
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Ziyat, H., Ait Itto, M. Y., Ali, M. A., Riahi, A., Karim, A., & Daran, J. C. (2006). Convenient synthesis of new functionalized cyclopropanes from monoterpenic olefines. Arkivoc, 2006(12), 152–160. https://doi.org/10.3998/ark.5550190.0007.c18
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