Exploring the impact of various reducing agents on Cu nanocluster synthesis

Abstract

The synthesis of copper (Cu) nanoclusters (NCs) has experienced significant advancements in recent years. Despite the exploration of metal NCs dating back almost two decades, challenges specific to Cu NC synthesis arise from the variable oxidation states and heightened reactivity of intermediate Cu complexes, distinguishing it from its analogous counterparts. In this study, we present a comprehensive overview of this newly evolving research domain, focusing on the synthetic aspects. We delve into various factors influencing the synthesis of Cu NCs, with specific emphasis on the role of reducing agents. The impact of the reducing agent is particularly pivotal in this synthetic process, ultimately influencing the formation of model M(0)-containing NCs, which are less readily accessible in the context of Cu NCs. We anticipate that this frontier article will pave the way for accelerated research in the field of Cu NCs. By aiding in the selection of specific reaction conditions and reducing agents, we believe that this work will contribute to a faster-paced exploration of Cu NCs, further advancing our understanding and applications in this exciting area of nanomaterial research.