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Polymer-supported dicyanoketene acetal as a π-acid catalyst: Monothioacetalization and carbon-carbon bond formation of acetals

Chemical and Pharmaceutical Bulletin (2000) 48(7) 1010-1016
DOI: 10.1248/cpb.48.1010
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Abstract

Polymeric dicyanoketene acetals (DCKA) were synthesized by copolymerization of styrene and divinylbenzene or ethylene glycol dimethacrylate. These novel polymers could be used successfully as recyclable π-acid catalysts in monothioaCetalization or carbon-carbon bond forming reaction of acetals.

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Tanaka, N., Miura, T., & Masaki, Y. (2000). Polymer-supported dicyanoketene acetal as a π-acid catalyst: Monothioacetalization and carbon-carbon bond formation of acetals. Chemical and Pharmaceutical Bulletin, 48(7), 1010–1016. https://doi.org/10.1248/cpb.48.1010

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