The intermediate frequency modes of single- And double-walled carbon nanotubes: A Raman spectroscopic and in situ Raman spectroelectrochemical study

Abstract

The intermediate frequency modes (IFM) of single-walled carbon nanotubes (SWCNTs) and double-walled carbon nanotubes (DWCNTs) were analyzed by Raman spectroscopy and in situ Raman spectroclectrochemistry. The inner and outer tubes of DWCNTs manifested themselves as distinct bands in the I FM region. This confirmed the diameter dependence of IFM frequencies. Furthermore, the analysis of inner tubes of DWCNTs allowed a more-precise assignment of the bands in the IFM region to features intrinsic for carbon nanotubes. Although the inner tubes in DWCNTs are assumed to be structurally perfect, the role of defects on IFM was discussed. The dependence of IFM on electrochemical charging was also studied. In situ spectroelectrochemical data provide a means to distinguish the bands of the outer and inner tubes. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.