Cold deep subduction recorded by remnants of a Paleoproterozoic carbonated slab

Abstract

The absence of low-thermal gradients in old metamorphic rocks (<350 °C GPa-1) has been used to argue for a fundamental change in the style of plate tectonics during the Neoproterozoic Era. Here, we report data from an eclogite xenolith in Paleoproterozoic carbonatite in the North China craton that argues for cold subduction as early as 1.8 Ga. The carbonatite has a sediment-derived C isotope signature and enriched initial Sr-Nd isotope composition, indicative of ocean-crust components in the source. The eclogite records peak metamorphic pressures of 2.5-2.8 GPa at 650-670 °C, indicating a cold thermal gradient, 250(±15) °C GPa-1. Our data, combined with old lowerature events in the West African and North American cratons, reveal a global pattern that modern-style subduction may have been established during the Paleoproterozoic Era. Paleoproterozoic carbonatites are closely associated with granulites and eclogites in orogens worldwide, playing a critical role in the Columbia supercontinent amalgamation and deep carbon cycle through time.