Non‐Covalent Interaction on the Self‐Healing of Mechanical Properties in Supramolecular Polymers

Abstract

Supramolecular polymers are widely utilized and applied in self–assembly or self–healing materials, which can be repaired when damaged. Normally, the healing process is classified into two types, including extrinsic and intrinsic self–healable materials. Therefore, the aim of this work is to review the intrinsic self–healing strategy based on supramolecular interaction or non‐covalent interaction and molecular recognition to obtain the improvement of mechanical properties. In this review, we introduce the main background of non‐covalent interaction, which consists of the metal– ligand coordination, hydrogen bonding, π–π interaction, electrostatic interaction, dipole–dipole interaction, and host–guest interactions, respectively. From the perspective of mechanical properties, these interactions act as transient crosslinking points to both prevent and repair the broken polymer chains. For material utilization in terms of self–healing products, this knowledge can be applied and developed to increase the lifetime of the products, causing rapid healing and reducing accidents and maintenance costs. Therefore, the self–healing materials using supramolecular polymers or non‐covalent interaction provides a novel strategy to enhance the mechanical properties of materials causing the extended cycling lifetime of products before replacement with a new one.