Abstract
Novel stable carbanions of the general formula -C(SO2CF3)n(CN)3-n (n = 1,2) were synthesized. The solid-state structure of cesium cyanobis(trifluoromethylsulfonyl)methanide was determined by single-crystal X-ray diffraction. Phenyldiazonium cyanobis(triluoromethylsulfonyl)-methanide underwent decomposition to yield the oxo-sulfonium ylide - trifluoromethyl(phenoxy)oxosulfonium cyano(trifluoromethylsulfonyl)methanide. © 1998 John Wiley & Sons, Inc.
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CITATION STYLE
Yagupolskii, Y. L., Pavlenko, N. V., & Lork, E. (1998). Trifluoromethylsulfonylmethanides functionalized by a CN group. Heteroatom Chemistry, 9(6), 565–570. https://doi.org/10.1002/(SICI)1098-1071(1998)9:6<565::AID-HC7>3.0.CO;2-3
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