Abstract
A new potassium iron (III) pyrophosphate was synthesized by hydrothermal technique and characterized by X-ray studies. The compound crystallizes in a monoclinic space group, P21/c, with cell parameters, a = 7-365(2) Å, b = 10.017(2) Å, c = 8-214(1) Å, β = 106-50(1)° and Z = 4. The structure has tunnel-type cavities and are congenial for ion transportation through them. The compound exhibits moderate thermal stability.
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Gopalakrishna, G. S., Doreswamy, B. H., Mahesh, M. J., Mahendra, M., Sridhar, M. A., Prasad, J. S., & Ashamanjari, K. G. (2005). Hydrothermal synthesis, structure and characterization of new NASICON related potassium iron (III) pyrophosphate. Bulletin of Materials Science, 28(1), 1–7. https://doi.org/10.1007/BF02711164
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