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Asymmetric Total Synthesis of Naphthospironone A

Angewandte Chemie - International Edition (2023) 62(22)
DOI: 10.1002/anie.202303229
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Abstract

Naphthospironone A, a polyhydroxy cagelike bioactive natural product, was synthesised for the first time in this study. The spiro[bicyclo[3.2.1]octane-pyran] core was constructed by an acid-promoted epoxide-opening lactonisation and a base-induced intramolecular aldol-type cyclisation.

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Liu, J. X., Zhang, S. P., Sun, F. S., Li, H., Gong, Y. L., Lu, S. C., & Xu, S. (2023). Asymmetric Total Synthesis of Naphthospironone A. Angewandte Chemie - International Edition, 62(22). https://doi.org/10.1002/anie.202303229

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