Enhanced hydrogen storage properties of magnesium hydride by multifunctional carbon-based materials: A review

Abstract

Hydrogen, known for its renewable nature, high energy utilization efficiency, and clean combustion, holds significant importance as a component in future energy systems. However, the development of an economical, safe, and efficient method for hydrogen storage remains a formidable challenge. In recent decades, researchers have made significant progress in achieving reversible hydrogen absorption and release using various metal hydrides. Among them, magnesium hydride (MgH2) has attracted considerable attention for its high energy density, low cost, and good reversibility. Nevertheless, the high hydrogen absorption and desorption temperature, sluggish kinetic properties, and poor cycling performance of MgH2 remain as the bottlenecks for its practical application. To mitigate these deficiencies, significant research efforts have been focused on the development of carbon-based materials as a means of preparing multifunctional materials. Carbon-based materials have demonstrated great potential in facilitating synergistic modification strategies, such as nanosizing, catalytic effects, and spatial confinement, which have been proven effective in enhancing the hydrogen storage performance of MgH2. In this paper, we present a comprehensive overview of various carbon-based materials, highlighting their unique properties and their contribution to improving hydrogen storage within MgH2 matrices. To be specific, we have been systematically reviewed the synergistic impacts of carbon materials, metal-organic frameworks, transition metal carbides (MXenes), and their respective composites on enhancing the hydrogen storage performance of MgH2. Additionally, this study underscores the benefits of utilizing multifunctional carbon-based materials as modifiers for MgH2 and proposes potential avenues for academic research.