Abstract
MOFs scattering away: The mechanism behind the multistep synthesis of two metal-organic frameworks sharing the same metal and organic precursors was revealed by in situ time-resolved small- and wide-angle X-ray scattering. Key factors governing the crystal assembly could be established (see picture: C gray, H white, N blue, O red, Al yellow, Cl green), including solvent, temperature, and precursor concentration. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Stavitski, E., Goesten, M., Juan-Alcañiz, J., Martinez-Joaristi, A., Serra-Crespo, P., Petukhov, A. V., … Kapteijn, F. (2011). Kinetic control of metal-organic framework crystallization investigated by time-resolved in situ X-ray scattering. Angewandte Chemie - International Edition, 50(41), 9624–9628. https://doi.org/10.1002/anie.201101757
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