Abstract
Touch, Pauson, engage: To explain the unique superior reactivity and stereoselectivity of O-tethered enynes in asymmetric Pauson-Khand type reaction (APKR) than their congeners, the internal-chelation to metal of oxygen atom of the substrate in the transition state was proposed. This proposition was well supported by APKR with several different substrates. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Kim, D. E., Park, S. H., Choi, Y. H., Lee, S. G., Moon, D., Seo, J., & Jeong, N. (2011). Internal chelation-guided regio- and stereoselective Pauson-Khand-type reaction by chiral Rhodium(I) catalysis. Chemistry - An Asian Journal, 6(8), 2009–2014. https://doi.org/10.1002/asia.201100271
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