Chlorido(2,3,7,8,12,13,17,18-octa-ethyl-porphyrinato)iron(III) dichloro-methane sesquisolvate

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Abstract

The title molecule, [Fe(C36H44N4)Cl] ·1.5CH2Cl2, is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065 (3) Å and an axial Fe-Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates.

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Safo, M. K., Buentello, K. E., Oliver, A. G., & Scheidt, W. R. (2010). Chlorido(2,3,7,8,12,13,17,18-octa-ethyl-porphyrinato)iron(III) dichloro-methane sesquisolvate. Acta Crystallographica Section E: Structure Reports Online, 66(7). https://doi.org/10.1107/S1600536810020015

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