Nonrelativistic limit of the Dirac-Fock equations

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Abstract

In this paper, the Hartree-Fock equations are proved to be the non relativistic limit of the Dirac-Fock equations as far as convergence of "stationary states" is concerned. This property is used to derive a meaningful definition of "ground state" energy and "ground state" solutions for the Dirac-Fock model.

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Esteban, M. J., & Séré, E. (2001). Nonrelativistic limit of the Dirac-Fock equations. Annales Henri Poincare, 2(5), 941–961. https://doi.org/10.1007/s00023-001-8600-7

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