A facile preparation of superhydrophobic L-CNC-coated meshes for oil-water separation

Abstract

A superhydrophobic stainless steel mesh (called “mesh” in short) is an ideal device to solve oil pollution accidents by oil-water separation. However, its widespread application is prevented by complicated preparation, weak durability, and particularly poor mechanical strength. It is well known that the used adhesives play a key role in the mechanical strength of superhydrophobic coatings. In this study, polyvinylidene fluoride (PVDF) and polydimethylsiloxanes (PDMSs) were respectively used as adhesives and lignin-nanocellulose crystal (L-CNC) particles as main structure materials to prepare L-CNC coated superhydrophobic meshes. Moreover, the meshes coated with L-CNC/PVDF and L-CNC/PDMS were compared with respect to the properties of wettability, sandpaper abrasion, oil-water separation,etc.The results showed that the L-CNC/PVDF-coated mesh had a higher water contact angle (WCA = 154.2°) than the L-CNC/PDMS-coated one (WCA = 152.6°), but worse abrasion resistance. Both of them showed high-efficiency oil/water separation with collection rates above 94.5% and stable reusable ability as the oil collection rates for toluene was still above 93.8% after reusing thirty times, meanwhile showing good heat, UV, acid and alkaline resistance properties.