Methylene blue adsorption onto cockle shells-treated banana pith: Optimization, isotherm, kinetic, and thermodynamic studies

Abstract

Two low-cost wastes, banana pith (BP) and cockle shells (CS) were explored towards methylene blue (MB) removal. The performance of cockle shells-treated banana pith (CS-BP) in MB removal was compared with untreated BP and commercially Ca(OH)2-treated BP (Ca(OH)2-BP). The adsorption efficacy was following the order of BP < CS-BP 0.99) and the Langmuir isotherm (R2 = 0.999) models, demonstrating the chemisorption and naturally homogeneous process. Thermodynamics study discovered that the MB removal by CS-BP is endothermic, feasible, spontaneous and randomness growth at a solid-solute interface. It is affirmed that CS could be employed as a low-cost activation material and CS-BP as a low-cost adsorbent.