Surface modification of gold by carbazole dendrimers for improved carbon dioxide electroreduction

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Abstract

Four types of carbazole dendrimers were applied as modification molecules of Au surfaces to improve carbon dioxide electroreduction. The reduction properties depended on the molecular structures: the highest activity and selectivity to CO was achieved by 9-phenylcarbazole, probably caused by the charge transfer from the molecule to Au.

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Yoshida, S., Sampei, M., Todoroki, N., Hisamura, E., Nakao, K., Albrecht, K., & Wadayama, T. (2023). Surface modification of gold by carbazole dendrimers for improved carbon dioxide electroreduction. Chemical Communications, 59(23), 3459–3462. https://doi.org/10.1039/d3cc00350g

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