Abstract
In situ neutron diffraction was used to study the structural properties of an industrial ammonia synthesis catalyst under working conditions similar to those of the Haber-Bosch process. Despite favorable thermodynamics, no indications of reversible bulk nitridation of the iron catalyst was observed in a self-generated ammonia concentration of 12 vol % at 425 °C and 75 bar after 88 h on stream. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Kandemir, T., Schuster, M. E., Senyshyn, A., Behrens, M., & Schlögl, R. (2013). The Haber-Bosch process revisited: On the real structure and stability of “ammonia iron” under working conditions. Angewandte Chemie - International Edition, 52(48), 12723–12726. https://doi.org/10.1002/anie.201305812
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