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Chiral phosphine Lewis bases in catalytic, asymmetric aza-Morita-Baylis- Hillman reaction

Pure and Applied Chemistry (2005) 77(12) 2105-2110
DOI: 10.1351/pac200577122105
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Abstract

In the aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with methyl vinyl ketone (MVK) promoted by chiral phosphine Lewis base: (A)-2′-diphenylphosphanyl-[1,1′]binaphthalenyl-2-ol (LB1) (10 mol%), the aza-Morita-Baylis-Hillman adducts were obtained in good yields with high ee (70-94% ee) at -30 °C in THF. The scope and limitations of this reaction have been disclosed. © 2005 IUPAC.

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Shi, M., & Chen, L. H. (2005). Chiral phosphine Lewis bases in catalytic, asymmetric aza-Morita-Baylis- Hillman reaction. In Pure and Applied Chemistry (Vol. 77, pp. 2105–2110). https://doi.org/10.1351/pac200577122105

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